I assume this is the original Stereomour, not the current Stereomour II? And I am guessing you are in Europe, from your name?
You are correct, a filter before the Stereomour will not affect the hum, which is 100Hz when the power is 50Hz and the filament gets AC power. (In 60Hz countries, residual hum is 120Hz.)
You can create a highpass after the 2A3 by replacing the parafeed capacitor with a smaller one. If the corner frequency is 200Hz, it would attenuate the 100Hz hum by 6dB - audible but not a lot. However, this will not attenuate the output at the driver resonance frequency where its impedance is much higher than in the midrange.
An interesting possibility is to put the driver in a very small box, around 5 liter for instance. This would raise the resonance to around 200Hz, with a QT=1.0 highpass response. In that case, you might see 12dB attenuation of the 100Hz hum without adding any filters. This would not be as simple as it sounds of course!