Hello Bryan,
The 0.1uF coupling capacitor value is reasonably well set in stone, it in combination with the 249K resistor that follows it provides a -3dB point of about 6 Hz. You could go slightly larger in that capacitor, but you'll just be paying more for another few tenths of a Hz, which seems less than sensible.
The parallel feed capacitor is a whole different animal, and its sizing can be optimized based on your room and speakers. PJ recommends buying a pair of 6.8uF/630V Solens, then trying the stock 3.3uF, the 6.8uF, and the two in parallel (about 10uF) and listening for bass extension and/or bass distortion (so listen loudly).
-PB