I am disturbed by the Pin 1 - pin 4 voltage difference, which should be 2.5vDC for a 2A3 in Paramount. Your data show 8v on one tube and 0v on the other, probably due to power line fluctuations during the measuring time. If they have equal dull red filament glow then all is fine there.
If the filaments are OK, then at first glance it appears output tube A is toast, with an exhausted cathode. To test this, you can swap the tubes side to side to see if the erroneous voltage at pins 1 and 4 follows the tube.
What is the make and model of the tubes being used? Are they the original 2006 tubes? Some models are more sensitive to the startup transient, and a worn tube will also be more sensitive to this.