No - the stripe on electrolytics is the negative so it goes to the load (headphones), but in the case of films it's good practice to put the outer foil to the lowest impedance, normally that's the 6080 cathode, with the inner foil to the headphones.
But, as robertone1 said, it is not important, partly because this is the highest signal voltage so there is almost no chance of picking up hum from electric fields that is actually audible, no matter which way the orientation goes.