Just make sure that your step-up trannie has separate primaries and secondaries, some of the cheaper ones are simply auto-transformers, with one tapped winding, which means that the higher voltage output is still "hot" as it has a more or less direct connection to the AC power line.
I've used 115/230VAC step-ups, and 115/115 isolation trannies for B+ supplies on several occasions. The isolations need to use a voltage doubler, to obtain B+ of about 275-300VDC, the step ups require a fullwave four diode bridge, for the same range of B+ voltages. .
Check out AnTek (johnango on ebay) he has a wide range of very reasonablly priced toriods, including 120+120VAC: 120+120VAC four-winding toroids which can be used for step up or step down purposes. If you're not drawing ehavy current, then three windings could be connected in series to make it a 120:360VAC step up. He also has a wide range of 50, 100, 200, 300 and 400VA tube PSU toriods of a wide range of secondary voltages. He is locaed in NJ, though I suspect that the trannies are manufactured over in Asia, which isn't a problem for me....
http://www.antekinc.com/index.php/ed B in NC