So terminal 1 now has high voltage again? Do both sides of the 12AU7 glow? If one of the LED's isn't lighting, then either that side of the tube isn't getting heat, the LED isn't properly soldered, or the 22K resistor between T1 and T2 isn't properly soldered.
Plugging in the headphones will have no influence on the LED's, the headphone output it on the opposite side of the circuit, isolated by the 6080 and coupling caps.
I wouldn't just replace the LED again, there is some evidence that this wasn't the problem to begin with. Check the connections and components that go to A4/5, A6, A7, and A9.