Hey Thermioniclife:
Well, I am really glad I asked my question before plugging in my phones. Thanks VERY much for your response. But, this is perplexing. I literally changed nothing other than the jack from TRS to XLR. I wired WHITE (formerly TIP) to pin 1, BLACK to pin 2 (with a jumper to pin 4), and RED to pin 3. I didn't touch the coupling caps and the unit worked fine with the TRS jack last night. All voltages pass with the XLR jack in there with the exception of checking pins 1 and 3 of the XLR jack (78 VDC on each).
There are resistors from TIP and RING on the TRS jack to ground (on the jack). Does there need to be resistors on the XLR jack as well? From looking at the Mainline, there are no resistors on either the TS or the XLR jacks. I am rather confused.