Bypassing in crossovers is a time honored tradition. A ballpark estimate of what value to use is 1/100 to 1/10 of the nameplate value of the existing capacitor. Since most capacitors are +/- 10% the combination will be within the intended tolerance of the designer.
What to use is anyone's guess. Although it is recognized that you should use a
better capacitor than the existing capacitor. So if there is an electrolytic,
any film capacitor will sound better. There are Metalized Film, Polyester Film, PETP Film Polystyrene Film, Polypropylene Film and Teflon (PTFE) Film capacitors. And probably quite a few I missed. I tried to put them in the order of better sound but I probably screwed that up too! I should also add that the USSR Military Surplus capacitors (some of us refer to them as KKs), including some POI capacitors they sell, are among the better and cheaper ones out there.
Although I have no experience with bypassing crossover capacitors I have done this in audio gear and have always been happy with the outcome. No, I have been happy enough with putting my first KK Teflon capacitors that I have bought large batches of Teflon 0.1uF@200V KP-2 KKs and put them everywhere in my system. I have purchased KKs in specific values for equipment I intend to buy. And a few values just in case I can find a good place to put them.
Ok, it is an illness, but you can buy a small batch for the price of 2 of the "designer" caps and have some fun with them.
Teflon capacitors need a longer than average breakin period. Here is my post on a relative painless method, you don't have to listen to them when they are not at their best, to break in capacitors:
Fast Breakin PostI hope this is somewhat helpful.