You mention a Crack, but have posted in the Paramount forum. If you are going to use it as the last cap in a Paramount, it should be rated for 600 volts DC.
Many people on the forums will try to tell you with great authority how to calculate the DC rating from the AC rating, but only the manufacturer knows for sure!. Many things go into that calculation, and most of them are not specified even if you knew what they were and how to use them in the calculation. Find the specification for that capacitor and see what the DC rating is. If the manufacturer will not provide a DC rating, I would advise not to use it in a DC power supply.
As to effect, I never met a power supply improvement that was not an audible improvement, so this (if it's safe and reliable) would probably be an improvement. Not as large an improvement as it would with a series feed amp, but probably audible.