John,
Generally caps are chosen relatively close to their working voltage (safety margin added of course) as in the same circuit the higher voltage cap will generally have higher ESR and inductance. In this situation, how much that will effect the sound, I can't even begin to guess but I'd say it might be pretty minimal. Electrolytics are another story though...
HTH,
Jim
Jim Rebman -- recovering audiophile
Equitech balanced power; uRendu, USB processor -> Musette DAC -> 5670 tube buffer -> Finale Audio F138 FFX -> Cain and Cain Abbys near-field).
s.e.x. 2.1 under construction. Want list: Stereomour II
All ICs homemade (speaker and power next)