In the Stereomour, the "design center" value is 2.5uF for 2A3 and 5uF for the 45. (This is because the 45 uses a different tap on the plate choke, with different inductance.)
The range of good values is broad, nominally from 1/2 to 2 times the design center. For that reason we ship with the 3.3uF which splits the difference and always works no matter which way you build it.
In the past I have provided theoretical guesses about the audible effect of different cap values, but I have come to the conclusion that the effect of different speakers is larger than that of caps, so it's best to experiment with your own speakers (in your own room) in order to find a meaningful optimum value. I use the stock values at home in my SEX and Paramount amps, but I have invested in Auricaps. YMMV.