OK, with the information given, it only took a few minutes to make some really nice graphs using Geogebra. The function I used looked like this:
f(x) = 10log(10, x) + 97
The log(10, x) is Geogebra's way of doing a base 10 log. The 97 represents a 97dB efficient speaker. f(x) will be the sound level in dB and x will represent the given watts. I can graph several functions using different efficiencies and compare them on the graph.
So, the next thing to blow their little minds with is the fact that the volume knob isn't linear. With a 100 watt amp, you don't hit 1 watt at 1/10th the rotation. Back in the 70s I had a 75 wpc amp that hit 1 watt around 1/3 of the rotation and 10 at around 2/3 of the rotation.
I was also thinking about the maximum sound a given speaker can produce. Certainly speakers have limits on the watts they can handle, but ignoring that, the most they can do will be limited by the size of the cone and the amount of excursion. This is my hunch, am I thinking right?
On one website I noticed them citing the loudest noise possible was 194dB. This must have something to do with the ability of air to transmit sound.
This has been very interesting research and I really appreciate all the help everyone has given.