What is "PM"?
There are tradeoffs between power, distortion, and damping factor, which could be exploited to get a bit more power at a sonic price. These involve changing the transformer wiring, or substituting a different transformer.
Basically though, it's like asking to double the horsepower in a car - it really makes best sense to get a different car (or amplifier) that is designed to produce the desired power.
You can in theory convert a SEX amp to parallel or to push-pull operation. Going with the car analogy, it's like strapping two motorcycles together to get a car. You can get double the power, and maybe more with push-pull, but it's complicated, untested, and you need another amp to get stereo.