If A5 and A4 touch, that will also throw off the DC voltages, but certainly I would do some trimming if they look close.
The first test you can do with the amp off, which is to measure the AC voltage between the center post of the 9 pin socket and ground (you can use the shell of the RCA jack) with the trim pot all the way up.
I typically use a free tone generator app on an old phone to get the 60Hz file. You can also use a laptop with a headphone jack and grab a tone generator webpage. Your DVM will read 60Hz AC, and typically I'd expect about 0.3V of signal to be available.