Hard to say. With 300Bs, I've tried the stock EH, Genalex, and new production WE. The EH and Genalex sounded pretty much alike but the WE is in a whole different league, but for $1500 a pair they damn well better be. Is the improvement in sound commensurate with the difference in cost? Probably not, but I'd say they're at least twice as good (though I don't really know how to quantify such judgments).
With 5670s, I've tried the stock GE (1980s production), older GEs (1950s), Sylvania 2C51s, a pair of WE 396A, and older 3-mica RCAs. I like the RCAs the best, but I could live happily with any of them except the WEs. They sound underwhelming.
Tube rolling 300Bs gets expensive quickly. 5670s are pretty cheap (within the context of vintage tube prices anyway), so that's where I'd suggest you experiment.