I still don't understand, is it a bad idea to switch them only when the amp is on, or bad idea in general even when the amp is off and unplugged?
My idea was that after I turn the amp off and unplug it, I switch both of the switches to the "discharge" position to bleed them through their respective discharge resistors, then switch both of the switches back to the "off" position, thereby taking both of the caps out of the circuit. Then by switching one or the other switch to the "cap on" position it would essentially be like having only the one cap directly soldered in, then I can plug the amp back in and turn it on??